Spectroscopic analysis and molecular structures of mononuclear bis(t-butyltrithiocarbonato)-nickel, -palladium and (t-butyltrithiocarbonato)(t-butylthiolato)platinum dimer was written by El-khateeb, Mohammad;Moriyama, Hayato;Yoshida, Yukihiro;Kitagawa, Hiroshi. And the article was included in Inorganica Chimica Acta in 2021.Application of 29364-29-2 This article mentions the following:
Treatment of the bis(triphenylphosphine)dichlorometal (PPh3)2MCl2 (M = Ni, Pd, Pt) with the trithiocarbonato anion (ButSCS–2) gave products depending on the metal center. In case of nickel, the product is Ni(κ2S,S-S2CSBut)2 (1) while for the palladium case, a similar complex Pd(κ2S,S-S2CSBut)2 (2) was obtained in addition to the dithiocarbonato complex (PPh3)2Pd(κ2S,S-S2C:O). However, the platinum reaction gave two products, a dimeric species Pt2(μ-SBut)2(κ2S,S-S2CSBut)2 (3) and the known trithiocarbonato complex (PPh3)2Pt(κ2S,S-S2C:S). These products were characterized by IR, 1H, 13C{1H} NMR and UV-Vis spectroscopy. Crystal structures of these complexes were determined by single crystal x-ray diffraction measurements. In the experiment, the researchers used many compounds, for example, Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2Application of 29364-29-2).
Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.Application of 29364-29-2
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts