Fine tuning of the orifice size of an open-cage fullerene by placing selenium in the rim: insertion/release of molecular hydrogen was written by Chuang, Shih-Ching;Murata, Yasujiro;Murata, Michihisa;Mori, Sadayuki;Maeda, Shuhei;Tanabe, Fumiyuki;Komatsu, Koichi. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2007.Name: Sodium 2-methyl-2-propanethiolate This article mentions the following:
A newly synthesized open-cage fullerene containing Se in the rim of the 13-membered-ring orifice allows milder conditions for H insertion, and the rate for H release is ca. three times faster than its S analog. In the experiment, the researchers used many compounds, for example, Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2Name: Sodium 2-methyl-2-propanethiolate).
Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Name: Sodium 2-methyl-2-propanethiolate
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts