Asymmetric transfer hydrogenation of ketones in 2-propanol catalyzed by arsinooxazoline-ruthenium(II) complex was written by Tan, Duan-Ming;Chan, Kin Shing. And the article was included in Tetrahedron Letters in 2005.Quality Control of (R)-1-(3-Chlorophenyl)ethanol This article mentions the following:
Chiral arsinooxazoline Ru(II) complex was an efficient catalyst for asym. transfer hydrogenation of aromatic ketones in 2-propanol. Secondary alcs. with up to 94% enantiomeric excess were obtained at a substrate/catalyst mole ratio of 1000:1. Asym. kinetic resolution was also obtained with 1-arylalkanols at room temperature with 99% ee. In the experiment, the researchers used many compounds, for example, (R)-1-(3-Chlorophenyl)ethanol (cas: 120121-01-9Quality Control of (R)-1-(3-Chlorophenyl)ethanol).
(R)-1-(3-Chlorophenyl)ethanol (cas: 120121-01-9) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. Alcohols may be oxidized to give ketones, aldehydes, and carboxylic acids. These functional groups are useful for further reactions. Oxidation of organic compounds generally increases the number of bonds from carbon to oxygen (or another electronegative element, such as a halogen), and it may decrease the number of bonds to hydrogen.Quality Control of (R)-1-(3-Chlorophenyl)ethanol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts