Nanoscale Assembly of CdS/BiVO4 Hybrids for Coupling Selective Fine Chemical Synthesis and Hydrogen Production under Visible Light was written by Shang, Feng-Kang;Qi, Ming-Yu;Tan, Chang-Long;Tang, Zi-Rong;Xu, Yi-Jun. And the article was included in ACS Physical Chemistry Au in 2022.Product Details of 873-76-7 This article mentions the following:
Simultaneously utilizing photogenerated electrons and holes in one photocatalytic system to synthesize value-added chems. and clean hydrogen (H2) energy meets the development requirements of green chem. Herein, we report a binary material of CdS/BiVO4 combining one-dimensional (1D) CdS nanorods (NRs) with two-dimensional (2D) BiVO4 nanosheets (NSs) constructed through a facile electrostatic self-assembly procedure for the selectively photocatalytic oxidation of aromatic alcs. integrated with H2 production, which exhibits significantly enhanced photocatalytic performance. Within 2 h, the conversion of aromatic alcs. over CdS/BiVO4-25 was approx. 9-fold and 40-fold higher than that over pure CdS and BiVO4, resp. The remarkably improved photoactivity of CdS/BiVO4 hybrids is mainly ascribed to the Z-scheme charge separation mechanism in the 1D/2D heterostructure derived from the interface contact between CdS and BiVO4, which not only facilitates the separation and transfer of charge carriers, but also maintains the strong reducibility of photogenerated electrons and strong oxidizability of photogenerated holes. It is anticipated that this work will further stimulate interest in the rational design of 1D/2D Z-scheme heterostructure photocatalysts for the selective fine chem. synthesis integrated with H2 evolution. In the experiment, the researchers used many compounds, for example, (4-Chlorophenyl)methanol (cas: 873-76-7Product Details of 873-76-7).
(4-Chlorophenyl)methanol (cas: 873-76-7) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.Product Details of 873-76-7
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts