Halobenzyl alcohols as structurally simple organogelators was written by Prathap, Annamalai;Ravi, Arthi;Pathan, Javed R.;Sureshan, Kana M.. And the article was included in CrystEngComm in 2019.Recommanded Product: 1777-82-8 This article mentions the following:
We report 11 simple halobenzyl alcs., each comprising of only 16 atoms, as organogelators for aliphatic hydrocarbon solvents. Comparison of PXRD profiles of wet gels and xerogels with the simulated profiles from the single crystal XRD data confirmed that the mol. packing in gels and crystals are identical. Therefore single crystal X-ray structures were analyzed to understand the mol. level interactions involved in the self-assembly in gel state. Each of these compounds undergoes a faster linear assembly along the crystallog. direction associated with the OH···O hydrogen bond and a supplementary non-covalent interaction (NCI). In directions perpendicular to the direction of OH···O Hydrogen bonding, mols. associate through various relatively weaker NCIs. Notably, halogen bonds, X···X, C-H···X interactions play major role in the lateral growth. In the case of gels, the linear growth is faster than lateral growth leading to the formation of long fibers, which entangles to a 3D fibrous network. This study reveals that halogen atoms in halobenzyl alcs. impart mol. features that contribute to their self-assembly in solution and hence in gelation. In the experiment, the researchers used many compounds, for example, (2,4-Dichlorophenyl)methanol (cas: 1777-82-8Recommanded Product: 1777-82-8).
(2,4-Dichlorophenyl)methanol (cas: 1777-82-8) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. Alcohols may be oxidized to give ketones, aldehydes, and carboxylic acids. These functional groups are useful for further reactions. Oxidation of organic compounds generally increases the number of bonds from carbon to oxygen (or another electronegative element, such as a halogen), and it may decrease the number of bonds to hydrogen.Recommanded Product: 1777-82-8
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts