Reinvestigating FeBr3-Catalyzed Alcohol Oxidation with H2O2: Is High-valent Iron Species (HIS) or Reactive Brominating Species (RBS) Responsible for Alcohol Oxidation? was written by He, Chenxi;Ma, Foqing;Zhang, Wei;Tong, Rongbiao. And the article was included in Organic Letters in 2022.Related Products of 873-76-7 This article mentions the following:
The in-situ generated RBS from the related FeBr2/H2O2 or CeBr3/H2O2 systems, (2) This results of a series of controlled experiments, and (3) some related RBS-based precedents (NBS, NBA, or Br2) showing similar high oxidation selectivity of secondary over primary alcs. These studies enable to discover that RBS from CeBr3/H2O2 was much more efficient for the oxidation of secondary and benzylic alcs., which represents a new green protocol for selective oxidation of alcs. to carbonyls. In the experiment, the researchers used many compounds, for example, (4-Chlorophenyl)methanol (cas: 873-76-7Related Products of 873-76-7).
(4-Chlorophenyl)methanol (cas: 873-76-7) belongs to alcohols. Under appropriate conditions, inorganic acids also react with alcohols to form esters. To form these esters, a wide variety of specialized reagents and conditions can be used. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.Related Products of 873-76-7
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts