Visible Light-Induced Hydrosilylation of Electron-Deficient Alkenes by Iron Catalysis was written by Ding, Ling;Niu, Kaikai;Liu, Yuxiu;Wang, Qingmin. And the article was included in ChemSusChem in 2022.SDS of cas: 2216-51-5 This article mentions the following:
Regioselective photochem. hydrosilylation of activated alkenes R1CH:CR2(EWG) with Ph3SiH catalyzed by iron trichloride, afforded linear triphenylsilanes Ph3SiCHR1CHR2(EWG) (R1, R2 = H, Me, CF3, CO2Me; EWG = carboxylate, CN, CHO, CONHPh). Herein, we reported a method for iron-catalyzed, visible-light-induced hydrosilylation reactions of electron-deficient alkenes to produce value-added silicon compounds Alkenes bearing functional groups with different steric properties were suitable substrates, as were derivatives of structurally complex natural products. Mechanistic studies showed that chlorine radicals generated by iron-catalyzed ligand-to-metal charge transfer in the presence of lithium chloride promoted the formation of silyl radicals. In the experiment, the researchers used many compounds, for example, (1R,2S,5R)-2-Isopropyl-5-methylcyclohexanol (cas: 2216-51-5SDS of cas: 2216-51-5).
(1R,2S,5R)-2-Isopropyl-5-methylcyclohexanol (cas: 2216-51-5) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.SDS of cas: 2216-51-5
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts