Sellmann, Dieter et al. published their research in European Journal of Inorganic Chemistry in 2002 | CAS: 29364-29-2

Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2) belongs to alcohols. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.Recommanded Product: 29364-29-2

Highly soluble sulfur-rich [Ni(L)(siS3)] complexes containing the new ligand bis(2-mercapto-3-trimethylsilylphenyl) sulfide(2-) (siS32-) was written by Sellmann, Dieter;Prakash, Raju;Geipel, Franz;Heinemann, Frank W.. And the article was included in European Journal of Inorganic Chemistry in 2002.Recommanded Product: 29364-29-2 This article mentions the following:

The new organosulfur ligands siS3-H2 [siS32- = bis(2-mercapto-3-trimethylsilylphenyl) sulfide(2-)] and caS3-H2 [caS32- = bis(2-mercapto-3-carboxyphenyl) sulfide(2-)] were synthesized from HS3-H2 [HS32- = bis(2-mercaptophenyl) sulfide(2-)], BuLi, and Me3SiCl or CO2/H+. Reaction of siS3-H2 with Ni(acac)2·4H2O gave the air-stable and well-soluble trinuclear complex I, [Ni(siS3)]3 (1), whose structure was determined by x-ray crystallog. Reactions of complex 1 with nucleophiles L [L = PR3 (R = Pr, Ph, Cy), N2H4, StBu–, and Cl–] yielded the corresponding neutral or anionic complexes, which were isolated as [Ni(PR3)(siS3)] [R = Pr (2), Ph (3), Cy (4)], Bu4N[Ni(Cl)(siS3)] (5), Bu4N[Ni(StBu)(siS3)] (6), and [Ni(N2H4)(siS3)] (8). The azido complex Et4N[Ni(N3)(siS3)] (7) was prepared from Me3SiN3 and the precursor chloro complex Et4N[Ni(Cl)(siS3)] formed in situ. Reaction of 1 with NH3 yielded labile [Ni(NH3)(siS3)] (9), which was characterized in solution by 1H and 13C NMR spectroscopy. Analogously, 1 reacts with nicotinamide (NA) or diethylnicotinamide (NAEt2) to give, from equilibrium reactions, the corresponding mononuclear [Ni(L)(siS3)] complexes with L = NA, NAEt2. X-ray structure determinations showed that 1, 3, 4, 5, and 7 all exhibit tetrahedrally distorted planar [Ni(L)(siS3)] fragments. Complex 7 is the first structurally characterized azidonickel complex with a coligand having exclusively S donors. In the experiment, the researchers used many compounds, for example, Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2Recommanded Product: 29364-29-2).

Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2) belongs to alcohols. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.Recommanded Product: 29364-29-2

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts