Photoreactivity of aqueous oxynitrogen anions (NOx-) with hydrocarbons. Part II. Aromatic and aliphatic compounds in nitrite was written by Petriconi, Gianna L.;Papee, Henry M.. And the article was included in Water, Air, and Soil Pollution in 1977.Application In Synthesis of rel-(1s,4s)-4-(2-Hydroxypropan-2-yl)-1-methylcyclohexanol hydrate This article mentions the following:
Research on NH4+ formation, by photoreduction under UV radiation of aqueous NO2- with suspended heptane [142-82-5], extended to C6H6 [71-43-2] and terpin hydrate [2451-01-6]. Radiation intensities similar to those found in nature were used this time with the purpose of determining, under laboratory conditions, overall rates of processes. The photolysis was carried out in a versatile apparatus and the results obtained are regarded as introductory towards investigations to be carried out under sunlight. While the formation of NH4+ in the NO2–heptane system follows the pattern previously outlined, thus confirming our earlier work, the reaction with the other compounds which contain either double bonds or OH groups follows a simpler route which involves much larger yields of NH4+ by attack of photoformed transients onto those reactive sites. In the experiment, the researchers used many compounds, for example, rel-(1s,4s)-4-(2-Hydroxypropan-2-yl)-1-methylcyclohexanol hydrate (cas: 2451-01-6Application In Synthesis of rel-(1s,4s)-4-(2-Hydroxypropan-2-yl)-1-methylcyclohexanol hydrate).
rel-(1s,4s)-4-(2-Hydroxypropan-2-yl)-1-methylcyclohexanol hydrate (cas: 2451-01-6) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. A multistep synthesis may use Grignard-like reactions to form an alcohol with the desired carbon structure, followed by reactions to convert the hydroxyl group of the alcohol to the desired functionality.Application In Synthesis of rel-(1s,4s)-4-(2-Hydroxypropan-2-yl)-1-methylcyclohexanol hydrate
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts