Facile design of degradable poly(β-thioester)s with tunable structure and functionality was written by Zaquen, Neomy;Wenn, Benjamin;Ranieri, Kayte;Vandenbergh, Joke;Junkers, Tanja. And the article was included in Journal of Polymer Science, Part A: Polymer Chemistry in 2014.Computed Properties of C10H14O5 This article mentions the following:
The synthesis of a range of linear biodegradable poly(β-thioester)s, PBTs, via hexylamine-catalyzed thiol-ene Micheal additions between a variety of diacrylate and dithiol monomers is described. Mol. weights up to 12,000 g mol-1 are obtained for this new class of polymer materials. PBTs featuring very different chem. and mech. behavior are obtained on the basis of seven diacrylate and three dithiol monomers. Polar PBTs are synthesized based on ethylene glycol-containing monomers in an environmentally friendly solvent. Furthermore, PBTs containing urethane units in the main chain are obtained, providing access to an isocyanate-free polyurethane polymerization method. The thiol-ene addition approach can also be used to couple polystyrene oligomers synthesized from a bifunctional trithiocarbonate reversible addition fragmentation transfer agent. In this way, PBTs featuring polystyrene segments as well as diacrylate segments are produced. In general for these step-growth polymerizations, by tuning the stoichiometric monomer ratio, a desired end group functionality can be quant. introduced into the PBT, which is demonstrated via soft ionization mass spectrometry anal. As an example, alkyne end groups have been built in, giving access to use these materials in modular polymer design strategies. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014. In the experiment, the researchers used many compounds, for example, Diethyleneglycoldiacrylate (cas: 4074-88-8Computed Properties of C10H14O5).
Diethyleneglycoldiacrylate (cas: 4074-88-8) belongs to alcohols. Under appropriate conditions, inorganic acids also react with alcohols to form esters. To form these esters, a wide variety of specialized reagents and conditions can be used. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.Computed Properties of C10H14O5
Referemce:
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Alcohols – Chemistry LibreTexts