Porous Chiral Metal-Organic Framework InH(D-C10H14O4)2 with Anionic-Type Diamond Network for High-Resolution Gas Chromatographic Enantioseparations was written by Xie, Sheng-Ming;Zhang, Xin-Huan;Zhang, Ze-Jun;Yuan, Li-Ming. And the article was included in Analytical Letters in 2013.Recommanded Product: (R)-2-Aminobutan-1-ol This article mentions the following:
Metal-organic frameworks have large surface area, highly ordered pore structure and good chem. stability. A porous chiral metal-organic framework InH(D-C10H14O4)2(D-C10H14O4 = D-(+)-camphoric acid) with a left-handed helical channel assembled from D-(+)-camphoric acid was used as chiral stationary phase in GC. InH(D-C10H14O4)2-coated open tubular columns with different inner diameters or lengths were prepared by a dynamic coating method for high-resolution GC separation of various types of organic compounds, including racemates, isomers, alkanes, alcs., and Grob’s test mixture Their column efficiency, polarity, and selectivity were studied. The stationary phase has excellent selectivity and also possesses good recognition ability toward these organic compounds, especially for chiral compounds In the experiment, the researchers used many compounds, for example, (R)-2-Aminobutan-1-ol (cas: 5856-63-3Recommanded Product: (R)-2-Aminobutan-1-ol).
(R)-2-Aminobutan-1-ol (cas: 5856-63-3) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.Recommanded Product: (R)-2-Aminobutan-1-ol
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