Metallo-Controlled Dynamic Molecular Tweezers: Design, Synthesis, and Self-Assembly by Metal-Ion Coordination was written by Ulrich, Sebastien;Petitjean, Anne;Lehn, Jean-Marie. And the article was included in European Journal of Inorganic Chemistry in 2010.Related Products of 79651-64-2 This article mentions the following:
The introduction of controllable dynamic features into synthetic receptors represents a step towards smart adaptive nanodevices. The authors report herein studies on the construction of dynamic mol. tweezers in which the binding of a substrate is allosterically controlled through shape switching of the receptor induced by metal-ion coordination. 1-dimensional, 2-dimensional NMR spectroscopy and x-ray crystallog. were used to identify the nature of the metallosupramol. entity generated. The presence of large aromatic naphthalene diimide moieties on the scaffold of the mol. tweezers strongly influences their coordination-driven self-assembly. These addnl. stacking interactions lead to the cooperative formation of a homocomplex, to the self-sorted assembly of a hetero complex, and to the binding of noncoordinating aromatic guests. In the experiment, the researchers used many compounds, for example, (6-Aminopyridin-2-yl)methanol (cas: 79651-64-2Related Products of 79651-64-2).
(6-Aminopyridin-2-yl)methanol (cas: 79651-64-2) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. Alcohols may be oxidized to give ketones, aldehydes, and carboxylic acids. These functional groups are useful for further reactions. Oxidation of organic compounds generally increases the number of bonds from carbon to oxygen (or another electronegative element, such as a halogen), and it may decrease the number of bonds to hydrogen.Related Products of 79651-64-2
Referemce:
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Alcohols – Chemistry LibreTexts