Polymeric organometallic architectures of novel P-Se anions was written by Shi, Weifeng;Shafaei-Fallah, Maryam;Zhang, Le;Anson, Christopher E.;Matern, Eberhard;Rothenberger, Alexander. And the article was included in Chemistry – A European Journal in 2007.Recommanded Product: Sodium 2-methyl-2-propanethiolate This article mentions the following:
The characterization of compounds obtained from Woollins’ reagent (W.R., PhP(Se)(μ-Se)2P(Se)Ph) offers a novel approach to organometallic coordination polymers. The syntheses were achieved by nucleophilic ring-opening reactions of W.R. with metal salts and crystallization using solvent-diffusion techniques. One-dimensional coordination polymers are formed as a result, and the dimensionality of the polymers can be influenced by using hydrated metal salts or by the construction of heterometallic arrangements. Compounds prepared and characterized by x-ray crystallog. include [K2(PhP(Se)(OtBu)Se)2(THF)]n, [Na2(SePhP(Se)-P(Se)PhSe)(THF)3]n, [K2(PhP(:Se)(Se–)Se-SeP(:Se)(Se–)Ph)(THF)4], [Na2(PhP(O)Se2)(H2O)4(THF)], [Ni{Na(PhPSe3)(THF)}2]n, and discrete cluster [Cu4(PhSeP-O-PSePh)2(PPh3)4]. In the experiment, the researchers used many compounds, for example, Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2Recommanded Product: Sodium 2-methyl-2-propanethiolate).
Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Recommanded Product: Sodium 2-methyl-2-propanethiolate
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