Stereochemical dominance in hierarchically formed helicates was written by Schlottmann, Marcel;Krueckel, Tobias;Albrecht, Markus. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2022.Synthetic Route of C10H20O This article mentions the following:
The competition of different chiral ligands in the control of stereochem. of hierarchically formed helical coordination compounds is investigated. It is found that sterically demanding chiral units can dominate the chiral induction of the helix even if they are present as a minor species. Hereby the relative strength of stereoinduction of different chiral units can be evaluated. In the experiment, the researchers used many compounds, for example, (1R,2S,5R)-2-Isopropyl-5-methylcyclohexanol (cas: 2216-51-5Synthetic Route of C10H20O).
(1R,2S,5R)-2-Isopropyl-5-methylcyclohexanol (cas: 2216-51-5) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.Synthetic Route of C10H20O
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts