Photochlorination of organic substances by aqueous chloride ions codissolved with anionic NOx–. Part I. Effect of nitrate was written by Rafanelli, Claudio E.;Petriconi, Gianna L.;Papee, Henry M.. And the article was included in Water, Air, and Soil Pollution in 1978.Category: alcohols-buliding-blocks This article mentions the following:
Earlier research, on the photoreactivity of some organics with aqueous NOx–, is extended to systems comprising codissolved chlorides. Concentrations of NO3– bear a determining role on the transfer of Cl from the aqueous into the organic phase, and rates of this transfer also depend on Cl– concentration as well as on the intensity of UV light. A simple overall mechanism is postulated for the laboratory process, and the experimentation is thereafter extended to conditions of sunlight illumination where the reaction occurs along similar lines but with larger quantum yields. In the experiment, the researchers used many compounds, for example, rel-(1s,4s)-4-(2-Hydroxypropan-2-yl)-1-methylcyclohexanol hydrate (cas: 2451-01-6Category: alcohols-buliding-blocks).
rel-(1s,4s)-4-(2-Hydroxypropan-2-yl)-1-methylcyclohexanol hydrate (cas: 2451-01-6) belongs to alcohols. Under appropriate conditions, inorganic acids also react with alcohols to form esters. To form these esters, a wide variety of specialized reagents and conditions can be used. Alcohols may be oxidized to give ketones, aldehydes, and carboxylic acids. These functional groups are useful for further reactions. Oxidation of organic compounds generally increases the number of bonds from carbon to oxygen (or another electronegative element, such as a halogen), and it may decrease the number of bonds to hydrogen.Category: alcohols-buliding-blocks
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts