N-Heterocyclic Carbene C,S Palladium(II) π-Allyl Complexes: Synthesis, Characterization, and Catalytic Application In Allylic Amination Reactions was written by Krishnan, Deepa;Wu, Meiyi;Chiang, Minyi;Li, Yongxin;Leung, Pak-Hing;Pullarkat, Sumod A.. And the article was included in Organometallics in 2013.HPLC of Formula: 29364-29-2 This article mentions the following:
Five-membered N-heterocyclic carbene C,S Pd(II) π-allyl complexes were successfully developed from the transmetalation of carbene silver complexes and characterized. Structural analyses of these complexes revealed that the organopalladium chelates adopt a skew-envelope conformation with a trans disposition of the substituents on the metal chelate rings. Using these C,S Pd(II) π-allyl complexes as catalysts, a catalytic system for the allylic amination reaction was developed. C-N bond formations between amines and unsym. substituted allylic carbonates could be catalyzed efficiently by complex (±)-9 in a regioselective manner. In the experiment, the researchers used many compounds, for example, Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2HPLC of Formula: 29364-29-2).
Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2) belongs to alcohols. A strong base can deprotonate an alcohol to yield an alkoxide ion (R―O−). For example, sodamide (NaNH2), a very strong base, abstracts the hydrogen atom of an alcohol. A multistep synthesis may use Grignard-like reactions to form an alcohol with the desired carbon structure, followed by reactions to convert the hydroxyl group of the alcohol to the desired functionality.HPLC of Formula: 29364-29-2
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts