Crystal structures of tetrakis-(4-chlorophenylthio)-butatriene and tetrakis-(tert-butylthio)-butatriene was written by Ibis, Cemil;Sayil, Cigdem;Deniz, N. Gulsah. And the article was included in Spectroscopy Letters in 2006.Formula: C4H9NaS This article mentions the following:
Tetrakis-(4-chlorophenylthio)-butatriene (3a) and tetrakis-(tert-butylthio)-butatriene (3b) were synthesized, and their crystal structures were determined The compound 3a is monoclinic, space group P21/c, a = 6.9785(8), b = 8.6803(9), c = 22.884(2) Å, β = 93.887(6)°, Z = 2. The compound 3b is monoclinic, space group P21/n, a = 11.0615(6), b = 10.8507(4), c = 11.2717(6) Å, β = 116.427(2)°, Z = 4. The title compounds 3a and 3b reside on an inversion center so that only half of the mol. is crystallog. unique. Both compounds are not planar. The crystal structures of 3a and 3b have cumulated double bonds. The C7-C8-C8i and C5-C6-C6i angles that show the linearity in both structures, resp., are 176.4(3)° in 3a and 175.6(2)° in 3b. In the experiment, the researchers used many compounds, for example, Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2Formula: C4H9NaS).
Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.Formula: C4H9NaS
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts