Nickel-Catalyzed Photodehalogenation of Aryl Bromides was written by Higginson, Bradley;Sanjose-Orduna, Jesus;Gu, Yiting;Martin, Ruben. And the article was included in Synlett in 2021.Synthetic Route of C12H16BBrO2 This article mentions the following:
Herein, Ni-catalyzed photodehalogenation of aryl bromides under visible-light irradiation that utilizes THF as hydrogen source were described. The protocol obviated the need for exogenous amine reductants or photocatalysts and was characterized by its simplicity and broad scope, including challenging substrate combinations. In the experiment, the researchers used many compounds, for example, 2-(4-Bromophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (cas: 68716-49-4Synthetic Route of C12H16BBrO2).
2-(4-Bromophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (cas: 68716-49-4) belongs to alcohols. Under appropriate conditions, inorganic acids also react with alcohols to form esters. To form these esters, a wide variety of specialized reagents and conditions can be used. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.Synthetic Route of C12H16BBrO2
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts