Influence of nanogel additive hydrophilicity on dental adhesive mechanical performance and dentin bonding was written by Gotti, Valeria B.;Correr, Americo B.;Lewis, Steven H.;Feitosa, Victor P.;Correr-Sobrinho, Lourenco;Stansbury, Jeffrey W.. And the article was included in Dental Materials in 2016.Product Details of 109-17-1 This article mentions the following:
To assess the influence of hydrophilicity of reactive nanogels on the mech. performance of dental adhesives and microtensile bond strength (μTBS) to dentin after 24 h or 3 mo of aging.A series of three nanogels were synthesized: NG1-IBMA/UDMA; NG2-HEMA/BisGMA; NG3-HEMA/TE-EGDMA. The nanogels were dispersed in solvent, HEMA or BisGMA/HEMA. The degree of conversion (DC) of the materials was measured and the flexural modulus of these polymers was evaluated in dry or wet conditions. For μTBS anal., a model adhesive was used without nanogel (control) or with the incorporation of nanogels. μTBS was evaluated after storage in distilled water for 24 h or 3 mo. The anal. of the fracture was performed after μTBS testing. Data were analyzed using ANOVA and Tukey’s test (α = 0.05).Water significantly increased the modulus of NG1 and NG2 dispersed in solvent, while significantly decreased the stiffness of NG3. All polymers dispersed in HEMA and BisGMA/HEMA had significantly lower modulus when stored in water. NG2 showed the highest DC in solvent and BisGMA/HEMA. In HEMA, NG1 and NG3 produced the highest DC. After three months, NG2 showed the best μTBS. The μTBS of NG2-containing adhesive resin significantly increased after 3 mo, while storage had no effect in the control group, NG1 and NG3.The more hydrophobic IBMA/UDMA nanogel showed higher bulk material mech. property results, but the best dentin bond strength values, and notably strength values that improved upon storage, were obtained with the amphiphilic nanogel based on BisGMA/HEMA. In the experiment, the researchers used many compounds, for example, ((Oxybis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl) bis(2-methylacrylate) (cas: 109-17-1Product Details of 109-17-1).
((Oxybis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl) bis(2-methylacrylate) (cas: 109-17-1) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.Product Details of 109-17-1
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Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts