A streamlined synthesis of extended thiophloroglucinol ligands and their trinuclear NiII3 complexes was written by Feldscher, Bastian;Theil, Hubert;Stammler, Anja;Boegge, Hartmut;Glaser, Thorsten. And the article was included in Dalton Transactions in 2014.Name: Sodium 2-methyl-2-propanethiolate This article mentions the following:
A protocol for the synthesis of trinucleating C3-sym. ligands based on a central meta-phenylene bridging 1,3,5-trimercaptobenzene (thiophloroglucinol) backbone was established. The key compound turned out to be the trialdehyde obtained from the triple nucleophilic attack of dimethyldithiocarbamate at 1,3,5-tribromo-2,4,6-triformylbenzene. Reacting this trialdehyde with six equivalent of a primary amine results in the simultaneous dithiocarbamate cleavage and Schiff-base formation providing the extended thiophloroglucinol ligands H3bertdien, H6bertMe, H6bertt-Bu2, and H6habbi. Reaction with NiII gives the trinuclear NiII3 complexes [(bertdien)NiII3](X)3 (X = BPh4–, BF4–), [(bertMe)NiII3], [(bertt-Bu2)NiII3], and [(habbi)NiII3], which were characterized spectroscopically, electrochem., and crystallog. In the experiment, the researchers used many compounds, for example, Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2Name: Sodium 2-methyl-2-propanethiolate).
Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.Name: Sodium 2-methyl-2-propanethiolate
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