Synthesis and structures of gallium alkoxides was written by Basharat, Siama;Knapp, Caroline E.;Carmalt, Claire J.;Barnett, Sarah A.;Tocher, Derek A.. And the article was included in New Journal of Chemistry in 2008.Electric Literature of C6H15NO This article mentions the following:
Homoleptic gallium tris(alkoxides), [Ga(OR)3]2 (R = CH2CH2NMe2 (2), CHMeCH2NMe2 (3), CMe2CH2OMe (4), CH2CH2OMe (5)), were prepared by the reaction of [Ga(NMe2)3]2 (1) and excess ROH in toluene at room temperature Compounds 2–5 were isolated as colorless oils. The side-products, [Ga(OCH2CH2NMe2)2Cl] (6), [Ga(OCHMeCH2NMe2)2Cl] (7) and [Ga(OCMe2CH2OMe)Cl2]2 (8) were also isolated in low yield during the synthesis of 2, 3 and 4, resp. However, compounds 6 and 7 were also prepared directly from the reaction of [Ga(NMe2)2Cl] and 2 equiv of ROH. Similarly, compound 8 was isolated from the reaction of [Ga(NMe2)Cl2] and 1 equiv of HOCMe2CH2OMe. Single crystal x-ray crystallog. showed that the gallium bis(alkoxides) (6 and 7) are monomeric in the solid state with the Ga center adopting a distorted trigonal bipyramidal geometry. In contrast, the gallium mono(alkoxide) 8 is dimeric. In the experiment, the researchers used many compounds, for example, 1-(Dimethylamino)-2-methylpropan-2-ol (cas: 14123-48-9Electric Literature of C6H15NO).
1-(Dimethylamino)-2-methylpropan-2-ol (cas: 14123-48-9) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Electric Literature of C6H15NO
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts