Efficient transfer hydrogenation of carbonyl compounds catalyzed by selenophenolato hydrido iron(II) complexes was written by Wang, Yangyang;Du, Zhengyin;Zheng, Tingting;Sun, Hongjian;Li, Xiaoyan. And the article was included in Catalysis Communications in 2019.Recommanded Product: 1777-82-8 This article mentions the following:
1,3-Cis-Selenophenolato hydrido iron(II) complexes I [R = H, 2-Me, 4-MeO] catalyzed transfer hydrogenation of aldehydes and ketones. Among the three complexes, catalyst I [R = H] exhibited the highest catalytic activity. The catalytic reactions took place under very mild conditions, using isopropanol as solvent and hydrogen source, tBuONa as base under 60-80°. This catalytic system had good tolerance for many functional groups, such as halides, C=C double bonds, nitro groups and cyano groups at the Ph ring of the substrates. In the experiment, the researchers used many compounds, for example, (2,4-Dichlorophenyl)methanol (cas: 1777-82-8Recommanded Product: 1777-82-8).
(2,4-Dichlorophenyl)methanol (cas: 1777-82-8) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.Recommanded Product: 1777-82-8
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts