Palladium aminopyridine complexes catalyzed selective benzylic C-H oxidations with peracetic acid was written by Lubov, Dmitry P.;Lyakin, Oleg Yu.;Samsonenko, Denis G.;Rybalova, Tatyana V.;Talsi, Evgenii P.;Bryliakov, Konstantin P.. And the article was included in Dalton Transactions in 2020.Synthetic Route of C7H9NO This article mentions the following:
Four palladium(II) complexes with tripodal ligands of the tpa family (tpa = tris(2-pyridylmethyl)amine) was synthesized and X-ray characterized. These complexes efficiently catalyzed benzylic C-H oxidation of various substrates with peracetic acid, affording the corresponding ketones in high yields (up to 100%), at < 1 mol% catalyst loadings. Complex [(tpa)Pd(OAc)](PF6) with the least sterically demanding ligand tpa demonstrated the highest substrate conversions and ketone selectivities. Preliminary mechanistic data provided evidence in favor of metal complex-mediated rate-limiting benzylic C-H bond cleavage by an electron-deficient oxidant. In the experiment, the researchers used many compounds, for example, 6-Methyl-2-pyridinemethanol (cas: 1122-71-0Synthetic Route of C7H9NO).
6-Methyl-2-pyridinemethanol (cas: 1122-71-0) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.Synthetic Route of C7H9NO
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts