A tunable synthesis of either benzaldehyde or benzoic acid through blue-violet LED irradiation using TBATB was written by Mardani, Atefeh;Heshami, Marouf;Shariati, Yadollah;Kazemi, Foad;Abdollahi Kakroudi, Mazaher;Kaboudin, Babak. And the article was included in Journal of Photochemistry and Photobiology, A: Chemistry in 2020.Application In Synthesis of (2,4-Dichlorophenyl)methanol This article mentions the following:
In this paper, a highly efficient, metal-free, and homogeneous method for the selective aerobic photooxidation of alcs. and photooxidative-desilylation of tert-butyldimethylsilyl ethers (TBDMS) in the presence of tetrabutylammonium tribromide (TBATB) under irradiation of visible light was reported. The light source: blue (460 nm) and violet (400 nm) LED, can control selective oxidation to aldehyde or carboxylic acid. In the experiment, the researchers used many compounds, for example, (2,4-Dichlorophenyl)methanol (cas: 1777-82-8Application In Synthesis of (2,4-Dichlorophenyl)methanol).
(2,4-Dichlorophenyl)methanol (cas: 1777-82-8) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. Alcohols may be oxidized to give ketones, aldehydes, and carboxylic acids. These functional groups are useful for further reactions. Oxidation of organic compounds generally increases the number of bonds from carbon to oxygen (or another electronegative element, such as a halogen), and it may decrease the number of bonds to hydrogen.Application In Synthesis of (2,4-Dichlorophenyl)methanol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts