Chiral Frustrated Lewis Pairs Catalyzed Highly Enantioselective Hydrosilylations of Ketones was written by Liu, Xiaoqin;Wang, Qiaotian;Han, Caifang;Feng, Xiangqing;Du, Haifeng. And the article was included in Chinese Journal of Chemistry in 2019.SDS of cas: 120121-01-9 This article mentions the following:
A highly enantioselective Piers-type hydrosilylation of simple ketones was successfully achieved using a chiral frustrated Lewis pair of tri-tert-butylphosphine and chiral diene-derived borane as catalyst. A wide range of optically active secondary alcs. were furnished in 80%-99% yields with 81%-97% ee’s under mild reaction conditions. In the experiment, the researchers used many compounds, for example, (R)-1-(3-Chlorophenyl)ethanol (cas: 120121-01-9SDS of cas: 120121-01-9).
(R)-1-(3-Chlorophenyl)ethanol (cas: 120121-01-9) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.SDS of cas: 120121-01-9
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts