New Stable Catalytic Electrodes Functionalized with TEMPO for the Waste-Free Oxidation of Alcohol was written by Karimi, Babak;Ghahremani, Mina;Ciriminna, Rosaria;Pagliaro, Mario. And the article was included in Organic Process Research & Development in 2018.Safety of (2,4-Dichlorophenyl)methanol This article mentions the following:
The authors report the 1st catalytically active and stable sol-gel electrode functionalized with the TEMPO moiety for the highly selective oxidation of alcs. with an elec. current only. The method shows broad applicability to different substrates, opening the route to the widespread adoption of this eminently clean technol. by the fine chem. and pharmaceutical industries. In the experiment, the researchers used many compounds, for example, (2,4-Dichlorophenyl)methanol (cas: 1777-82-8Safety of (2,4-Dichlorophenyl)methanol).
(2,4-Dichlorophenyl)methanol (cas: 1777-82-8) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.Safety of (2,4-Dichlorophenyl)methanol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts