Synthesis of 2-aminomethylpyridine-appended [60]fullerenes. On the difference in the metal-binding properties between 5,6-open and 6,6-closed isomers was written by Ikeda, Atsushi;Fukuhara, Chie;Shinkai, Seiji. And the article was included in Chemistry Letters in 1998.Reference of 1122-71-0 This article mentions the following:
Two 2-aminomethylpyridine-appended [60]fullerenes with the 5,6-open and the 6,6-closed structure were synthesized to examine the influence of the structural difference on the metal-binding ability. Both compounds could form the 1:1 complex with Ag+ but the Kass for the 5,6 isomer was larger by more than two orders of magnitude than that for the 6,6 isomer. In the experiment, the researchers used many compounds, for example, 6-Methyl-2-pyridinemethanol (cas: 1122-71-0Reference of 1122-71-0).
6-Methyl-2-pyridinemethanol (cas: 1122-71-0) belongs to alcohols. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.Reference of 1122-71-0
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts