Isomerization as a route to rare ketoses: the beneficial effect of microwave irradiation on Mo(VI)-catalyzed stereospecific rearrangement was written by Hricoviniova, Zuzana. And the article was included in Tetrahedron: Asymmetry in 2008.Electric Literature of C6H14O6 This article mentions the following:
Mo(VI)-catalyzed isomerization of easily accessible 2-C-(hydroxymethyl)-branched aldoses to rare ketoses was achieved in 3 min using microwave flash heating. This contribution highlights the remarkable advantages of Mo(VI) catalysis and the beneficial effects of microwave irradiation in carbohydrate synthesis. The transformation yielded the resp. ketoses in good yields (46-86%). Furthermore, the potential of the Mo(VI)-catalyzed transformation was studied using a new branched 6-deoxy-aldose to prepare 7-deoxy–gluco-heptulose. The method is fast and useful for the preparation of rare ketoses under microwave conditions. In the experiment, the researchers used many compounds, for example, (2R,3R,4S,5S)-2,3,4,5-tetrahydroxyhexanal hydrate (cas: 10030-85-0Electric Literature of C6H14O6).
(2R,3R,4S,5S)-2,3,4,5-tetrahydroxyhexanal hydrate (cas: 10030-85-0) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. Alcohols may be oxidized to give ketones, aldehydes, and carboxylic acids. These functional groups are useful for further reactions. Oxidation of organic compounds generally increases the number of bonds from carbon to oxygen (or another electronegative element, such as a halogen), and it may decrease the number of bonds to hydrogen.Electric Literature of C6H14O6
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts