Ultrafast and Stable CO2 Capture Using Alkali Metal Salt-Promoted MgO-CaCO3 Sorbents was written by Cui, Hongjie;Zhang, Qiming;Hu, Yuanwu;Peng, Chong;Fang, Xiangchen;Cheng, Zhenmin;Galvita, Vladimir V.;Zhou, Zhiming. And the article was included in ACS Applied Materials & Interfaces in 2018.Electric Literature of C6H20CaO11 This article mentions the following:
As a potential candidate for precombustion CO2 capture at intermediate temperatures (200-400 °C), MgO-based sorbents usually suffer from low kinetics and poor cyclic stability. Herein, a general and facile approach is proposed for the fabrication of high-performance MgO-based sorbents via incorporation of CaCO3 into MgO followed by deposition of a mixed alkali metal salt (AMS). The AMS-promoted MgO-CaCO3 sorbents are capable of adsorbing CO2 at an ultrafast rate, high capacity, and good stability. The CO2 uptake of sorbent can reach as high as above 0.5 gCO2 gsorbent-1 after only 5 min of sorption at 350 °C, accounting for vast majority of the total uptake. In addition, the sorbents are very stable even under severe but more realistic conditions (desorption in CO2 at 500 °C), where the CO2 uptake of the best sorbent is stabilized at 0.58 gCO2 gsorbent-1 in 20 consecutive cycles. The excellent CO2 capture performance of the sorbent is mainly due to the promoting effect of molten AMS, the rapid formation of CaMg(CO3)2, and the plate-like structure of sorbent. The exceptional ultrafast rate and the good stability of the AMS-promoted MgO-CaCO3 sorbents promise high potential for practical applications, such as precombustion CO2 capture from integrated gasification combined cycle plants and sorption-enhanced water gas shift process. In the experiment, the researchers used many compounds, for example, Calcium 2-hydroxypropanoate pentahydrate (cas: 5743-47-5Electric Literature of C6H20CaO11).
Calcium 2-hydroxypropanoate pentahydrate (cas: 5743-47-5) belongs to alcohols. Under appropriate conditions, inorganic acids also react with alcohols to form esters. To form these esters, a wide variety of specialized reagents and conditions can be used. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.Electric Literature of C6H20CaO11
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