Zhang, Xue-Zhen published the artcileSynthesis, Structures, and Fluorescence Properties of Dimeric Aluminum Oxo Clusters, COA of Formula: C11H8O3, the publication is Inorganic Chemistry (2021), 60(10), 7089-7093, database is CAplus and MEDLINE.
Aluminum is an important component for luminescence. However, the fluorescent aluminum complex with unambiguous structural information is still limited. Herein, we report a series of fluorescence aluminum oxo clusters (AlOCs). By introducing an addnl. coordination site to the aromatic conjugation ligand, cluster nuclearity increment and fluorescence variation are observed Al8(OH)2(μ4-O)2(1-NA)2(OEt)16 (AlOC-41, 1-NA = 1-naphthoic acid, OEt = ethanol) is made up of two tetrahedral subunits. By introducing an addnl. coordination site to the aromatic conjugation ligand, we isolate a high nuclearity compound Al10(μ3-O)2(3-HNA)2(OEt)22 (AlOC-47, 3-HNA = 3-hydroxy-2-naphthoic acid). Correspondingly, their luminescence performance is different (blue fluorescence in AlOC-41 and green in AlOC-47). Present herein is a platform to illustrate the relationship between synthesis, structure, and fluorescence properties.
Inorganic Chemistry published new progress about 86-48-6. 86-48-6 belongs to alcohols-buliding-blocks, auxiliary class Organic Pigment,Natural product, name is 1-Hydroxy-2-naphthoic acid, and the molecular formula is C23H43NP2, COA of Formula: C11H8O3.
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