Wen, Shang-Pin published the artcileRAFT miniemulsion polymerisation of benzyl methacrylate using non-ionic surfactant, Formula: C8H10S, the publication is Polymer Chemistry (2021), 12(14), 2122-2131, database is CAplus.
Miniemulsion polymerization has become widely recognized as a versatile and efficient strategy to prepare well-defined polymer latexes. In this article, we report the synthesis of poly(benzyl methacrylate) (PBzMA) latexes via reversible addition-fragmentation chain-transfer (RAFT) mediated miniemulsion polymerization using non-ionic Lutensol TO 20 surfactant. The influence of hydrophobe, initiator, and RAFT agent on particle diameter, particle number, rate of polymerization, and molar mass were investigated systematically. In all cases well-controlled RAFT polymerizations were observed, as indicated by kinetic studies and GPC anal. Higher concentrations of hexadecane lead to an increase in the of number of particles per unit volume and a decrease in PBzMA latex diameter The rate of polymerization with respect to initiator concentration follows a power-law relationship Rp α [initiator]1/2 but only negligible differences in molar mass, molar mass dispersity, and particle diameter values were observed for a range of initiator concentrations Targeting lower PBzMA degrees of polymerization increases the overall rate of polymerization and latex diameter
Polymer Chemistry published new progress about 4410-99-5. 4410-99-5 belongs to alcohols-buliding-blocks, auxiliary class Thiol,Benzene, name is 2-Phenylethanethiol, and the molecular formula is C21H20BrNO4S, Formula: C8H10S.
Referemce:
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