Wang, Xuewei published the artcileYnamide-Mediated Intermolecular Esterification, Recommanded Product: 4-(1H-Pyrrol-1-yl)phenol, the publication is Journal of Organic Chemistry (2020), 85(9), 6188-6194, database is CAplus and MEDLINE.
An ynamide-mediated one-pot, two-step intermol. esterification via the condensation of carboxylic acids with nucleophilic hydroxyl species is reported. A broad substrate scope with respect to carboxylic acids, alcs., and phenols is observed The α-acyloxyenamide intermediates formed by the addition of carboxylic acids to ynamides proved to be effective acylating reagents for the esterification of alc. and phenol derivatives with the assistance of base catalysis. Notably, the racemization of the α-chiral center of carboxylic acids can be avoided.
Journal of Organic Chemistry published new progress about 23351-09-9. 23351-09-9 belongs to alcohols-buliding-blocks, auxiliary class Pyrrole,Benzene,Alcohol, name is 4-(1H-Pyrrol-1-yl)phenol, and the molecular formula is C18H35NO, Recommanded Product: 4-(1H-Pyrrol-1-yl)phenol.
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