Wang, Bing-Lin’s team published research in Journal of Fluorine Chemistry in 127 | CAS: 83706-94-9

Journal of Fluorine Chemistry published new progress about 83706-94-9. 83706-94-9 belongs to alcohols-buliding-blocks, auxiliary class Trifluoromethylated Building Blocks, name is (E)-4,4,4-Trifluorobut-2-en-1-ol, and the molecular formula is C7H10N2O2, Formula: C4H5F3O.

Wang, Bing-Lin published the artcileSynthesis of trifluoromethylated analogues of α-L-fucofuranose and α-L-4,6-dideoxyxylohexopyranose, Formula: C4H5F3O, the publication is Journal of Fluorine Chemistry (2006), 127(4-5), 580-587, database is CAplus.

Efficient strategy to trifluoromethylated trans-disubstituted alkene I was developed starting from com. available 4,4,4-trifluoro-3-oxo-butyric acid Et ester. 6-Deoxy-6,6,6-trifluorosugars II and III were synthesized from I in high stereoselectivity and in a straightforward fashion. The key steps were Sharpless asym. dihydroxylation, regioselective ring opening of trifluoromethylated cyclic sulfate, Horner-Wadsworth-Emmons reaction, oxidation and intramol. heterocyclization. It was noteworthy that the oxidation of alcs. followed by deprotection and acetylation gave the single isomer target mols. II and III, resp.

Journal of Fluorine Chemistry published new progress about 83706-94-9. 83706-94-9 belongs to alcohols-buliding-blocks, auxiliary class Trifluoromethylated Building Blocks, name is (E)-4,4,4-Trifluorobut-2-en-1-ol, and the molecular formula is C7H10N2O2, Formula: C4H5F3O.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts