Smirnov, Vladimir I. published the artcileCrystal and molecular structures of Si-(iodomethyl)silatranes with methyl substituents in β-position relative to the nitrogen atom, COA of Formula: C9H21NO3, the publication is Mendeleev Communications (2018), 28(3), 278-280, database is CAplus.
Crystal and mol. structures of two silatranes, 1-iodomethyl-3-methyl- and 1-iodomethyl-3,7,10-trimethyl-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecanes, were determined by X-ray anal. Comparison of their structural and geometrical characteristics with those of other silatranes shows that the presence of Me substituents β-positioned to nitrogen atoms increases the length of the dative Si←N bond, whereas the introduction of iodine into the axial position of the silatrane slightly decreases the length of the Si←N bond.
Mendeleev Communications published new progress about 122-20-3. 122-20-3 belongs to alcohols-buliding-blocks, auxiliary class Organic Pigment, name is Triisopropanolamine, and the molecular formula is C16H20N2, COA of Formula: C9H21NO3.
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