Shi, Lei published the artcileRapid and Efficient Microwave-Assisted Amination of Electron-Rich Aryl Halides without a Transition-Metal Catalyst, Related Products of alcohols-buliding-blocks, the publication is Organic Letters (2003), 5(19), 3515-3517, database is CAplus and MEDLINE.
A rapid and direct amination of aryl halides has been developed, in good to high yields, under microwave irradiation without a transition-metal catalyst. This reaction is a particularly powerful method for the coupling of electron-rich aryl halides with various amines. In some cases, excellent regioselectivity could be observed, which facilitated the preparation of meta-substituted anilines, e.g., I, from ortho- or para-substituted Ph halides. The proposed mechanism proceeds through a benzyne intermediate.
Organic Letters published new progress about 27292-49-5. 27292-49-5 belongs to alcohols-buliding-blocks, auxiliary class Morpholine,Benzene,Phenol, name is 3-Morpholinophenol, and the molecular formula is C15H18BF3O4, Related Products of alcohols-buliding-blocks.
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