Park, Myung Jun’s team published research in Main Group Metal Chemistry in 22 | CAS: 17877-23-5

Main Group Metal Chemistry published new progress about 17877-23-5. 17877-23-5 belongs to alcohols-buliding-blocks, auxiliary class Protection and Derivatization Reagent, name is Triisopropylsilanol, and the molecular formula is C9H22OSi, Application of Triisopropylsilanol.

Park, Myung Jun published the artcileDirect preparation of hexaalkyldisiloxanes from trialkylsilanes and cyclosiloxanes from dialkylsilanes using potassium superoxide-crown ether, Application of Triisopropylsilanol, the publication is Main Group Metal Chemistry (1999), 22(12), 713-714, database is CAplus.

Trialkysilanes, R1R2R3SiH (R1/R2/R3 = iPr/iPr/iPr, Et/Et/Et, Ph/Me/Me), were readily transformed to the corresponding hexaalkyldisiloxane in high yields with KO2-18-crown-6. Dialkylsilanes, R1R2SiH2 (R1/R2 = Ph/Ph, Ph/Me, n-Oct/Me, c-hex/Me, Et/Et) gave mainly octaalkylcyclotetrasiloxanes under the same reaction conditions.

Main Group Metal Chemistry published new progress about 17877-23-5. 17877-23-5 belongs to alcohols-buliding-blocks, auxiliary class Protection and Derivatization Reagent, name is Triisopropylsilanol, and the molecular formula is C9H22OSi, Application of Triisopropylsilanol.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts