Liu, Xiaojie published the artcileNi-Catalyzed Deoxygenative Borylation of Phenols Via O-Phenyl-uronium Activation, Formula: C10H9NO, the publication is ACS Catalysis (2022), 12(15), 8904-8910, database is CAplus.
Herein, we report an efficient method for the Ni-catalyzed deoxygenative borylation of unprotected phenols and also demonstrate that this Ni-catalyzed phenolic C(sp2)-O transformation is applicable to the Suzuki-Miyaura-type and Heck-type cross-couplings of phenols. Investigations on the reaction intermediate have revealed that the achievement of general, mild deoxygenative cross-coupling reactions of phenols is ascribed to the conversion of phenols into the unusual O-phenyl-uroniums that feature active phenolic C(sp2)-O bonds. The Ni-complex intermediate resulting from an oxidative addition of a phenolic C(sp2)-O bond to monophosphine-supported Ni(0) catalyst was characterized and confirmed to be (PCy3)2Ni(Ar)(F) complex, offering exptl. evidence for the generally proposed C(sp2)-O oxidative addition step.
ACS Catalysis published new progress about 23351-09-9. 23351-09-9 belongs to alcohols-buliding-blocks, auxiliary class Pyrrole,Benzene,Alcohol, name is 4-(1H-Pyrrol-1-yl)phenol, and the molecular formula is C10H9NO, Formula: C10H9NO.
Referemce:
https://en.wikipedia.org/wiki/Alcohol,
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