Li, Dan published the artcileDesymmetrization Process by Mg(II)-Catalyzed Intramolecular Vinylogous Michael Reaction, Recommanded Product: 4-Propylphenol, the publication is Organic Letters (2020), 22(23), 9229-9233, database is CAplus and MEDLINE.
Chiral magnesium catalyzed intramol. vinylogous Michael reaction of novel cyclohexadienones via a desymmetrization process is reported. (R)-BINOL derived ligand and an achiral amide were employed in the current in situ generated magnesium catalyst, giving the corresponding hydrogenated benzofuranone skeletons in good to excellent enantioselectivities with high yields. This simple and efficient strategy could be utilized for the synthesis of aromatized α,β-unsaturated ester and Br-substituted hydrogenated benzofuranone in good yields under mild conditions.
Organic Letters published new progress about 645-56-7. 645-56-7 belongs to alcohols-buliding-blocks, auxiliary class Liquid Crystal &OLED Materials, name is 4-Propylphenol, and the molecular formula is C9H12O, Recommanded Product: 4-Propylphenol.
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