Urayama, Teppei published the artcileO2-enhanced catalytic activity of gold nanoparticles in selective oxidation of hydrosilanes to silanols, Recommanded Product: Triisopropylsilanol, the publication is Chemistry Letters (2015), 44(8), 1062-1064, database is CAplus.
O2 acts as a nonconsumed activator for gold nanoparticles (AuNPs) in the oxidation of hydrosilanes to silanols with water under O2 atm, providing an acceleration of more than 200 times relative to the reaction rate under Ar atm. The AuNP catalyst under aerobic conditions exhibits high activity in the oxidation with high turnover numbers (1230000). Various hydrosilanes including less-reactive bulky ones can be converted to the corresponding silanols in excellent yields. Moreover, the present AuNP catalyst is reusable while maintaining the high performance.
Chemistry Letters published new progress about 17877-23-5. 17877-23-5 belongs to alcohols-buliding-blocks, auxiliary class Protection and Derivatization Reagent, name is Triisopropylsilanol, and the molecular formula is C22H18Cl2N2, Recommanded Product: Triisopropylsilanol.
Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts