Journal of Organic Chemistry published new progress about 85618-21-9. 85618-21-9 belongs to alcohols-buliding-blocks, auxiliary class Tetrahydropyran,Chiral,sulfides,Alcohol, name is (2R,3S,4S,5R,6S)-2-(Hydroxymethyl)-6-(octylthio)tetrahydro-2H-pyran-3,4,5-triol, and the molecular formula is C9H6BrNO, SDS of cas: 85618-21-9.
Ueda, Yoshihiro published the artcileFunctional Group Tolerance in Organo-Catalytic Regioselective Acylation of Carbohydrates, SDS of cas: 85618-21-9, the publication is Journal of Organic Chemistry (2009), 74(22), 8802-8805, database is CAplus and MEDLINE.
Organo-catalytic regioselective acylation of mono- and disaccharides with various functionalized acid anhydrides has been developed. Acylation of octyl β-D-glucopyranoside with acid anhydrides derived from α-amino acids, cinnamic acid, and gallic acid took place at C(4)-OH with 67-94% regioselectivity in the presence of catalyst I. Regioselective acylation of disaccharides with functionalized acid anhydrides was also achieved with 78-94% selectivity. Especially, a disaccharide with seven free hydroxy groups (X = OH, R’ = H) underwent acylation at C(4)-OH with 78% regioselectivity in the presence of I. Thus, functional group tolerance in the regioselective acylation catalyzed by I was found to be high.
Journal of Organic Chemistry published new progress about 85618-21-9. 85618-21-9 belongs to alcohols-buliding-blocks, auxiliary class Tetrahydropyran,Chiral,sulfides,Alcohol, name is (2R,3S,4S,5R,6S)-2-(Hydroxymethyl)-6-(octylthio)tetrahydro-2H-pyran-3,4,5-triol, and the molecular formula is C9H6BrNO, SDS of cas: 85618-21-9.
Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts