Su, Xinluona published the artcileDiffusion of phenolic compounds within high-silica MFI-type zeolite in the mesitylene solution, Category: alcohols-buliding-blocks, the publication is Microporous and Mesoporous Materials (2021), 111044, database is CAplus.
The intracrystalline diffusivity of phenolic compounds (phenol, p-propylphenol and m-cresol) and toluene within silicalite-1 and MFI-type zeolite with Si/Al = 303 (H-MFI) in the liquid phase (solvent: mesitylene) in the temperature range from 313 to 353 K were measured by using the constant volumetric method. The amounts of phenol, p-propylphenol, and toluene adsorbed onto silicalite-1 at 313, 323 and 353 K were approx. the same, whereas less m-cresol was adsorbed because of its larger kinetic diameter Unlike adsorbed toluene, adsorbed of phenol displayed stronger interactions in H-MFI than in silicalite-1, indicating that hydrogen bonding between the OH group of phenol and Bronsted acid sites in H-MFI enhanced the adsorption of phenol. Whereas the intracrystalline diffusivity of phenol, p-propylphenol, and toluene within silicalite-1 are approx. the same, m-cresol exhibited lower intracrystalline diffusivity, indicating that the intracrystalline diffusivity was governed by geometrical limitation. The intracrystalline diffusivity of phenol was lower within H-MFI with acid sites than within silicalite-1. The residence time of phenol on the acid sites became longer than that of toluene, which led to a difference in the intracrystalline diffusivity between phenol and toluene within H-MFI.
Microporous and Mesoporous Materials published new progress about 645-56-7. 645-56-7 belongs to alcohols-buliding-blocks, auxiliary class Liquid Crystal &OLED Materials, name is 4-Propylphenol, and the molecular formula is C20H17FO4S, Category: alcohols-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts