Sokolova, Daria published the artcileEnantioselective Tail-to-Head Terpene Cyclizations by Optically Active Hexameric Resorcin[4]arene Capsule Derivatives, Recommanded Product: cis-3,7-Dimethyl-2,6-Octadien-1-Ol, the publication is Angewandte Chemie, International Edition (2022), 61(25), e202203384, database is CAplus and MEDLINE.
Mol. capsules enabled the conversion of substrates inside a closed cavity, mimicking to some extent enzymic catalysis. Chirality transfer from the mol. capsule onto the encapsulated substrate was only studied in a few cases. Here the chirality transfer was possible inside a rather large mol. container of approx. 1400 S3 was demonstrated. Specifically, the first examples of optically active hexameric resorcin[4]arene capsules such as I [R = Et, n-Pr, n-Bu], their ability to enantioselectively catalyze tail-to-head terpene cyclizations, and the surprisingly high sensitivity of enantioselectivity on the structural modifications was presented.
Angewandte Chemie, International Edition published new progress about 106-25-2. 106-25-2 belongs to alcohols-buliding-blocks, auxiliary class Natural product, name is cis-3,7-Dimethyl-2,6-Octadien-1-Ol, and the molecular formula is C7H6O3, Recommanded Product: cis-3,7-Dimethyl-2,6-Octadien-1-Ol.
Referemce:
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