Sheykhan, Mehdi published the artcileNovel access to carbonyl and acetylated compounds: the role of the tetra-n-butylammonium bromide/sodium nitrite catalyst, HPLC of Formula: 101-98-4, the publication is RSC Advances (2016), 6(56), 51347-51355, database is CAplus.
A novel aerobic oxidation of alcs. ArCH(OH)R (Ar = C6H5, 2-O2N-3-CH3-C6H3, 2-carbaldehydefuran-5-yl, etc.; R = H, CH3) without the use of any oxidants was developed. An equimolar catalytic mixture of tetra-n-butylammonium bromide and sodium nitrite catalyzes the aerobic selective oxidation of benzylic alcs. under oxidant-free, base-free and metal-free conditions. The mild reaction conditions allow oxidation of a wide range of benzylic alcs., chemo-selectively to their carbonyl compounds ArC(O)R (68-93% isolated yields). More importantly, high selectivity among different kinds of alcs. (aromatic vs. aliphatic alcs., primary vs. secondary alcs. as well as alcs. having neutral rings vs. electron-deficient rings) is available by this approach. The method surprisingly switched over to be an efficient acetylation approach in the case of aliphatic alcs. without the use of any transition metal, phosphorus or other toxic reagents or any need for using toxic acyl halides, sulfonyl halides, anhydrides, etc. by the use of only acetic acid as a reagent.
RSC Advances published new progress about 101-98-4. 101-98-4 belongs to alcohols-buliding-blocks, auxiliary class Amine,Benzene,Alcohol, name is 2-(Benzyl(methyl)amino)ethanol, and the molecular formula is C16H24BF4Ir, HPLC of Formula: 101-98-4.
Referemce:
https://en.wikipedia.org/wiki/Alcohol,
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