Mizukado, Junji published the artcileInsertion reactions of difluorocarbene generated by pyrolysis of hexafluoropropene oxide to OH bond, Application In Synthesis of 2240-88-2, the publication is Journal of Fluorine Chemistry (2005), 126(3), 365-369, database is CAplus.
ROCHF2-type fluorinated ethers were synthesized by the reaction of hexafluoropropene oxide (HFPO) with alc. or phenol. In this reaction, although the insertion reaction of difluorocarbene to O-H bond and the nucleophilic attack of alc. or phenol to HFPO were competition, the insertion reaction proceeded predominantly to give fluorinated ether in the case of low nucleophilic alc. or phenol. In addition, high reaction pressure is advantageous to the selectivity of the fluorinated ethers in the reaction of HFPO with (CF3)2CHOH or C6F5OH.
Journal of Fluorine Chemistry published new progress about 2240-88-2. 2240-88-2 belongs to alcohols-buliding-blocks, auxiliary class Trifluoromethyl,Fluoride,Aliphatic hydrocarbon chain,Alcohol, name is 3,3,3-Trifluoropropan-1-ol, and the molecular formula is C3H5F3O, Application In Synthesis of 2240-88-2.
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