Mathis-Noel, Raymonde published the artcileSpectroscopic studies of hydrogen bonding in aliphatic and aromatic amino alcohols, Application of 2-(Benzyl(methyl)amino)ethanol, the publication is Bulletin de la Societe Chimique de France (1970), 3047-56, database is CAplus.
Inter- and intramol. H bonds were studied for a series of amino alcs., which included some aromatic substituted compounds The ir frequencies of the OH and NH bonds were observed for the pure compound and for several dilutions in CCl4. Further, the NMR shifts of these bonds were observed All compounds studied, with the one exception of 1-phenyl-2-N-methyl-N-ethylaminoethanol, showed various intermol. H-bonds in the pure phase, i.e., OH..A, NH…O, NH…N. Compounds with electron donor substituents on N showed intramol. H bonds (C. F. Douberet and Pariand, 1962). Such bonds are also observed for primary amines; they increase as the number of electron donors on the adjacent C increases. Substitution of an electron source or sink for a H on the C bearing the OH will always favor intramol. association Chelation will be suppressed by substitution of a H atom on N; this increases the H-bonding to the π-electrons of an aromatic system, observed at about 3541 cm-1.
Bulletin de la Societe Chimique de France published new progress about 101-98-4. 101-98-4 belongs to alcohols-buliding-blocks, auxiliary class Amine,Benzene,Alcohol, name is 2-(Benzyl(methyl)amino)ethanol, and the molecular formula is C10H15NO, Application of 2-(Benzyl(methyl)amino)ethanol.
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https://en.wikipedia.org/wiki/Alcohol,
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