Marciniec, Bogdan’s team published research in Tetrahedron Letters in 49 | CAS: 17877-23-5

Tetrahedron Letters published new progress about 17877-23-5. 17877-23-5 belongs to alcohols-buliding-blocks, auxiliary class Protection and Derivatization Reagent, name is Triisopropylsilanol, and the molecular formula is C9H22OSi, Name: Triisopropylsilanol.

Marciniec, Bogdan published the artcileSilylation of silanols with vinylsilanes catalyzed by a ruthenium complex, Name: Triisopropylsilanol, the publication is Tetrahedron Letters (2008), 49(8), 1310-1313, database is CAplus.

A new ruthenium complex-catalyzed O-silylation of silanols with vinylsilanes leading to siloxane bond formation with the evolution of ethylene is described. A maximum conversion of silanol is reached using an excess of vinylsilane which also yields the product of the homo-coupling of the latter. Under the optimum conditions, when a vinylsilane with at least one ethoxy substituent is used, the reaction gives exclusively unsym. siloxanes.

Tetrahedron Letters published new progress about 17877-23-5. 17877-23-5 belongs to alcohols-buliding-blocks, auxiliary class Protection and Derivatization Reagent, name is Triisopropylsilanol, and the molecular formula is C9H22OSi, Name: Triisopropylsilanol.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts