Hurley, Michael D. published the artcileAtmospheric Chemistry of CF3CH2CH2OH: Kinetics, Mechanisms and Products of Cl Atom and OH Radical Initiated Oxidation in the Presence and Absence of NOx, Application In Synthesis of 2240-88-2, the publication is Journal of Physical Chemistry A (2005), 109(43), 9816-9826, database is CAplus and MEDLINE.
Relative rate techniques were used to study the kinetics of the reactions of Cl atoms and OH radicals with CF3CH2C(O)H and CF3CH2CH2OH in 700 Torr of N2 or air diluent at 296 ± 2 K. The rate constants determined were k(Cl+CF3CH2C(O)H) = (1.81 ± 0.27) x 10-11, k(OH+CF3CH2C(O)H) = (2.57 ± 0.44) x 10-12, k(Cl+CF3CH2CH2OH) = (1.59 ± 0.20) x 10-11, and k(OH+CF3CH2CH2OH) = (6.91 ± 0.91) x 10-13 cm3 mol.-1 s-1. Product studies of the chlorine initiated oxidation of CF3CH2CH2OH in the absence of NO show the sole primary product to be CF3CH2C(O)H. Product studies of the chlorine initiated oxidation of CF3CH2CH2OH in the presence of NO show the primary products to be CF3CH2C(O)H (81%), HC(O)OH (10%), and CF3C(O)H. Product studies of the chlorine initiated oxidation of CF3CH2C(O)H in the absence of NO show the primary products to be CF3C(O)H (76%), CF3CH2C(O)OH (14%), and CF3CH2C(O)OOH (≤10%). As part of this work, an upper limit of k(O3+CF3CH2CH2OH) < 2 × 10-21 cm3 mol.-1 s-1 was established. Results are discussed with respect to the atm. chem. of fluorinated alcs.
Journal of Physical Chemistry A published new progress about 2240-88-2. 2240-88-2 belongs to alcohols-buliding-blocks, auxiliary class Trifluoromethyl,Fluoride,Aliphatic hydrocarbon chain,Alcohol, name is 3,3,3-Trifluoropropan-1-ol, and the molecular formula is C3H5F3O, Application In Synthesis of 2240-88-2.
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