Collins, Ian published the artcileN-alkenyl nitrone dipolar cycloaddition routes to piperidines and indolizidines. Part 6. Allylic stereocontrol in the intramolecular cyclization of monosubstituted nitrones, Related Products of alcohols-buliding-blocks, the publication is Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999) (1994), 2205-15, database is CAplus.
The intramol., thermal dipolar cycloadditions of the (Z)-N-alk-4-enyl nitrones I (R = OMe, MeOCH2O, alkylsiloxy) bearing a single, allylic substituent were investigated. Certain alkoxy substituted nitrones I showed a remarkable preference for the formation of axially substituted isoxazolidines II (same R), whereas the Pr and trifluoromethyl substituted nitrones I (R = F3C, Pr) gave equatorially substituted cycloadducts resp., consistent with the involvement of chair-like transition states.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999) published new progress about 83706-94-9. 83706-94-9 belongs to alcohols-buliding-blocks, auxiliary class Trifluoromethylated Building Blocks, name is (E)-4,4,4-Trifluorobut-2-en-1-ol, and the molecular formula is C4H5F3O, Related Products of alcohols-buliding-blocks.
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