Campisi, Sebastiano published the artcileFurfural Adsorption and Hydrogenation at the Oxide-Metal Interface: Evidence of the Support Influence on the Selectivity of Iridium-Based Catalysts, Formula: C5H12O2, the publication is ChemCatChem (2022), 14(6), e202101700, database is CAplus.
Here, tetrakis(hydroxymethyl)phosphonium chloride-protected colloidal iridium nanoparticles were deposited by sol-immobilization on three different supports (CeO2, NiO and TiO2) and were investigated for the liquid-phase direct hydrogenation (H2 atmosphere) and catalytic transfer hydrogenation – CTH (N2 atmosphere) of furfural to study the effect of the H donor. The occurrence of strong-metal support interactions in 1 wt % Ir/CeO2 catalyst, as disclosed by XPS, was revealed to be responsible for the high activity observed in the direct hydrogenation (81% conversion after 6 h) and for the unusual selectivity to 2-methylfuran (70%) under CTH conditions. On the other hand, Ir/NiO showed peculiar selectivity to tetrahydrofurfuryl alc. in both H2 and N2 atmospheres (71% and 70%, resp.). The d. functional theory calculations further showed that the unique selectivity of Ir/NiO may be ascribed to the adsorption properties of furfural on the support, which activates a dual-site hydrogenation mechanism.
ChemCatChem published new progress about 111-29-5. 111-29-5 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic hydrocarbon chain,Alcohol,Ploymers, name is Pentane-1,5-diol, and the molecular formula is C5H12O2, Formula: C5H12O2.
Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts