Azzena, Ugo published the artcileReductive cleavage of N-substituted 2-aryl-1,3-oxazolidines: generation of α-amino-substituted carbanions, SDS of cas: 101-98-4, the publication is Journal of Organic Chemistry (1993), 58(24), 6707-11, database is CAplus.
The behavior of N-substituted 2-aryl-1,3-oxazolidines I (R = H, Me, Ph, R1 = aryl, R2 = Me, Et) have been investigated under conditions of electron transfer from alkali metals in aprotic solvents. The reduction led to the regioselective cleavage of the benzylic carbon-oxygen bond, with formation of the corresponding N-substituted benzylamino alcs. RR1CHNR2CH2CH2OH in good yields. Investigation of the mechanism of this reductive cleavage, with the aid of labeling experiments, showed the intermediate formation of α-tertiary amino-substituted carbanions.
Journal of Organic Chemistry published new progress about 101-98-4. 101-98-4 belongs to alcohols-buliding-blocks, auxiliary class Amine,Benzene,Alcohol, name is 2-(Benzyl(methyl)amino)ethanol, and the molecular formula is C10H15NO, SDS of cas: 101-98-4.
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